Search Results

5.373 Dinitrogen Cleavage (New)

Prereq: 5.03, 5.363, Coreq: 5.61
U (Fall; partial term)
4 Units

Introduces the research area of small-molecule activation by transition-element complexes. Covers techniques such as glove-box methods for synthesis for exclusion of oxygen and water; filtration, reaction mixture concentration, and recrystallization under a dinitrogen atmosphere and under static vacuum. Characterization methods include proton NMR spectroscopy of both paramagnetic and diamagnetic systems, Evans method magnetic susceptibility measurement, UV-Vis spectroscopy, and infrared spectroscopy of a metal-nitrogen triple bond system.

C. Cummins

See more...

Institute for Data, Systems, and Society

...a score of 7.5 or better. Information...program office , Room E17-373, 617-258-7295...